Sengoden, Mani ; Bhowmick, Abhisikta ; Punniyamurthy, Tharmalingam (2017) Stereospecific copper-catalyzed domino ring opening and sp3 C–H functionalization of activated aziridines with N-alkylanilines Organic Letters, 19 (1). pp. 158-161. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/acs.orglett.6b...
Related URL: http://dx.doi.org/10.1021/acs.orglett.6b03458
Abstract
Copper efficiently catalyzed nucleophilic ring opening, sp3 C–H functionalization, and C–N bond formation in the presence of tert-butyl hydroperoxide to afford functionalized imidazolidines starting from N-sulfonylaziridines and N-alkylanilines. The products were obtained in high optical purities (95 → 99% ee) with excellent functional group tolerance.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 106973 |
| Deposited On: | 22 Jun 2017 09:57 |
| Last Modified: | 22 Jun 2017 09:57 |
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