Mahesh, Devulapally ; Sadhu, Pradeep ; Punniyamurthy, Tharmalingam (2016) Copper(II)-catalyzed oxidative cross-coupling of anilines, primary alkyl amines, and sodium azide using TBHP: a route to 2-substituted benzimidazoles The Journal of Organic Chemistry, 81 (8). pp. 3227-3234. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b0018...
Related URL: http://dx.doi.org/10.1021/acs.joc.6b00186
Abstract
Copper(II)-catalyzed oxidative cross-coupling of anilines, primary alkyl amines, and sodium azide is described in the presence of TBHP at moderate temperature. This one-pot multicomponent protocol involves a domino C–H functionalization, transimination, ortho-selective amination, and a cyclization sequence. The broad substrate scope and functional group compatibility are the significant practical features. The protocol can be extended to the coupling of benzyl alcohols with moderate yields.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 106954 |
| Deposited On: | 22 Jun 2017 10:00 |
| Last Modified: | 22 Jun 2017 10:00 |
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