Copper(II)-catalyzed direct dioxygenation of alkenes with air andn-hydroxyphthalimide: synthesis of β-keto-N-alkoxyphthalimides

Bag, Raghunath ; Sar, Dinabandhu ; Punniyamurthy, Tharmalingam (2015) Copper(II)-catalyzed direct dioxygenation of alkenes with air andn-hydroxyphthalimide: synthesis of β-keto-N-alkoxyphthalimides Organic Letters, 17 (8). pp. 2010-2013. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b...

Related URL: http://dx.doi.org/10.1021/acs.orglett.5b00770

Abstract

Copper(II)-catalyzed direct dioxygenation of alkenes using air and a simple N-hydroxyphthalimide leading to β-keto-N-alkoxyphthalimides has been developed. The reaction system is mild, efficient, and effective at room temperature with broad substrate scope and substantial steric hindrance. The radical-trapping and 18O-labeling experiments have been demonstrated.

Item Type:Article
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ID Code:106839
Deposited On:22 Jun 2017 10:07
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