Mahesh, Devulapally ; Sadhu, Pradeep ; Punniyamurthy, Tharmalingam (2015) Copper(I)-catalyzed regioselective amination of N-aryl imines using TMSN3 and TBHP: a route to substituted benzimidazoles Journal of Organic Chemistry, 80 (3). pp. 1644-1650. ISSN 0022-3263
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/jo502574u
Related URL: http://dx.doi.org/10.1021/jo502574u
Abstract
A novel and efficient copper-catalyzed amination of N-aryl imines is described. This one-pot, multicomponent reaction, in which imine acts as a directing group by chelating to the metal center, affords a potential route for the transformation of the commercial aryl amines, aldehydes, and azides into valuable benzimidazole structural units with wide substrate scope and diversity. The synthetic and mechanistic aspects are presented.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 106837 |
| Deposited On: | 22 Jun 2017 10:08 |
| Last Modified: | 22 Jun 2017 10:08 |
Repository Staff Only: item control page
