Design of neutral hydrocarbons having a planar tetracoordinate carbon

Priyakumar, U. Deva ; Sastry, G. Narahari (2004) Design of neutral hydrocarbons having a planar tetracoordinate carbon IJCA - International Journal of Computer Applications, 43A (3). pp. 455-457. ISSN 0975-8887

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Abstract

Cyclopropyne (C3H2) and related spiro bicyclic structures show unusual structural preference for the planar tetracoordinate structure over the conventional tetrahedral arrangement. C5H4 has been proposed as the smallest neutral hydrocarbon with planar tetracoordinate carbon . NICS values indicate substantial stabilization of the planar arrangements over the tetrahedral counterparts.

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