Priyakumar, U. Deva ; Reddy, A. Srinivas ; Sastry, G. Narahari (2004) The design of molecules containing planar tetracoordinate carbon Tetrahedron Letters, 45 (12). pp. 2495-2498. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.02.017
Abstract
A novel preference for planar tetracoordination was observed over the conventional tetrahedral arrangement in a new series of C5H2, C5H4, C5H41+/2+ and related compounds. The stability of these molecules is assessed with the ring-opening barriers, HOMO–LUMO gap, singlet–triplet energy differences and nucleus independent chemical shift values.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Planar Tetracoordinate Carbon; Aromatic Stabilization; Singlet–Triplet Gap; Ring-Opening Barrier; Nucleus Independent Chemical Shift |
ID Code: | 106651 |
Deposited On: | 28 Jul 2017 09:22 |
Last Modified: | 28 Jul 2017 09:22 |
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