Iodobenzene catalyzed C–H amination of N-substituted amidines using m-chloroperbenzoic acid

Alla, Santhosh Kumar ; Kumar, Rapolu Kiran ; Sadhu, Pradeep ; Punniyamurthy, Tharmalingam (2013) Iodobenzene catalyzed C–H amination of N-substituted amidines using m-chloroperbenzoic acid Organic Letters, 15 (6). pp. 1334-1337. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol400274f

Related URL: http://dx.doi.org/10.1021/ol400274f

Abstract

The oxidative C–H amination of N″-aryl-N′-tosyl/N′-methylsulfonylamidines and N,N′-bis(aryl)amidines has been accomplished using iodobenzene as a catalyst to furnish 1,2-disubstituted benzimidazoles in the presence of mCPBA as a terminal oxidant at room temperature. The reaction is general, and the target products can be obtained in moderate to high yields.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:106604
Deposited On:22 Jun 2017 10:13
Last Modified:22 Jun 2017 10:13

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