Jammi, Suribabu ; Ali, Md Ashif ; Sakthivel, Sekarpandi ; Rout, Laxmidhar ; Punniyamurthy, Tharmalingam (2009) Synthesis, structure, and application of self-assembled copper(II) aqua complex by H-bonding for acceleration of the nitroaldol reaction on water Chemistry - An Asian Journal, 4 (2). pp. 314-320. ISSN 1861-4728
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Official URL: http://onlinelibrary.wiley.com/wol1/doi/10.1002/as...
Related URL: http://dx.doi.org/10.1002/asia.200800339
Abstract
Simple addition: Copper(II) aqua complex 1 can be prepared in a one-pot synthesis and is self-assembled by H-bond interactions. Complex 1 is shown to accelerate the nitroaldol reaction on water, which is a heterogeneous process, requiring no additive or base, and 1 can be recycled without loss of activity. Copper(II) aqua complex 1 has been prepared in a one-pot synthesis. The single crystal X-ray analysis showed that the complex is self-assembled through aqua ligands by H-bond interactions and the copper(II) atoms are pentacoordinated with square pyramidal geometry. Complex 1 has been studied for the acceleration of the nitroalodol reaction on water. It is a clean technological process and the catalyst can be recycled without loss of activity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons Inc. |
| ID Code: | 106259 |
| Deposited On: | 22 Jun 2017 10:28 |
| Last Modified: | 22 Jun 2017 10:28 |
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