Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation

Punniyamurthy, Tharmalingam ; Mayr, Monika ; Dorofeev, Alexander S. ; Bataille, Carole J. R. ; Gosiewska, Silvia ; Nguyen, Bao ; Cowley, Andrew R. ; Brown, John M. (2008) Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation Chemical Communications, 2008 (41). pp. 5092-5094. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2008...

Related URL: http://dx.doi.org/10.1039/B807669C

Abstract

In situ resolution of the rapidly racemising diphosphine BIPHEP and its relatives with the cationic Rh complex of (S,S)-bicyclonona-2,6-diene permits the asymmetric hydrogenation of dehydroamino esters.

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