Jammi, Suribabu ; Rout, Laxmidhar ; Saha, Prasenjit ; Akkilagunta, Vijay K. ; Sanyasi, Sridhar ; Punniyamurthy, Tharmalingam (2008) Synthesis, structure and application of chiral copper(II) coordination polymers for asymmetric acylation Inorganic Chemistry, 47 (12). pp. 5093-5098. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic800228c
Related URL: http://dx.doi.org/10.1021/ic800228c
Abstract
Chiral copper(II) coordination polymers 1a−c have been prepared by one-pot synthesis in high yield. Their single-crystal X-ray analysis showed that repeating units are connected to each other by carboxylate linker and copper(II) atoms are pentacoordinated with distorted square-pyramidal geometry for 1a−b and square-planar geometry for 1c. These polymers have catalyzed the kinetic resolution of secondary alcohols by acylation with up to 90% ee (s = 50).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 106256 |
| Deposited On: | 22 Jun 2017 10:29 |
| Last Modified: | 22 Jun 2017 10:29 |
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