Gurjar, Mukund K. ; Pedduri, Yakambram ; Ramana, C .V. ; Puranik, Vedavati G. ; Gonnade, Rajesh G. (2004) Toward a synthesis of the antitumor macrolide peloruside A: A chiral pool approach for the C(1)–C(11) segment Tetrahedron letters, 45 (2). pp. 387-390. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2003.10.153
Abstract
Dihydroxylation of the glucose derived α,β-unsaturated lactones 6 and 13 was found to be on the α-face of the pyranolactone ring exclusively. The resulting dihydroxylated compound from 13 has been used in a synthesis of the lactone 4, which corresponds to C(1)–C(11) of peloruside A.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Barbies Reaction; Ring Closing Metathesis; Dihydroxylation; Barton–McCombie Deoxygenation; Mitsunobu Reaction; Dess–Martin Periodinane |
| ID Code: | 106167 |
| Deposited On: | 01 Feb 2018 16:57 |
| Last Modified: | 01 Feb 2018 16:57 |
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