Ramana, C. V. ; Sridhar Reddy, Bethi ; Gurjar, Mukund K. (2004) Synthesis of differentially protected cyclopentitol: Its application towards the stereoselective synthesis of 5-epi-calditol Tetrahedron letters, 45 (13). pp. 2817-2819. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.02.020
Abstract
The synthesis of differentially protected cyclopentitol derivative 5 is described using ring-closing metathesis of a diene derived from d-mannose. Subsequent chemical modifications such as catalytic osmylation and chain extension using glycidyl triflate completed the synthesis of 5-epi-calditol.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Calditol; Cyclopentitols; Ring Closing Metathesis; Second Generation Grubbs’ Catalyst; Catalytic Osmylation |
| ID Code: | 106166 |
| Deposited On: | 01 Feb 2018 16:57 |
| Last Modified: | 01 Feb 2018 16:57 |
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