Ramana, C. V. ; Giri, Awadut G. ; Suryawanshi, Sharad B. ; Gonnade, Rajesh G. (2007) Total synthesis of pachastrissamine (jaspine B) enantiomers from D-glucose Tetrahedron Letters, 48 (2). pp. 265-268. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.11.048
Abstract
Synthesis of both enantiomers of pachastrissamine is described from a common chiral template. The stereoselective construction of the central tetrahydrofuran units was based on the pseudodesymmetrization of a pentodialdo-1,4-furanose derivative taking advantage of the latent symmetry present.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Chiron Approach; Pachastrissamine/Jaspine B; Pentodialdo-1,4-Furanose; Ohira–Bestmann Reaction; Ring Isomerization |
| ID Code: | 106155 |
| Deposited On: | 01 Feb 2018 16:56 |
| Last Modified: | 01 Feb 2018 16:56 |
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