Reddy, A. Chandrasekhar ; Sastry, G. Narahari ; Shaik, Sason (1995) Electron transfer mechanisms: a mechanistic changeover induced by an intramolecular spacer in a model reaction of the NH3/C2H4˙+pair Journal of the Chemical Society, Perkin Transactions 2 (9). pp. 1717-1719. ISSN 0300-9580
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1995...
Related URL: http://dx.doi.org/10.1039/P29950001717
Abstract
Computational evidence is reported for a reversal in the type of an electron transfer (ET) mechanism, induced by an intramolecular linkage of the donor (amine) and acceptor (cation radical) moieties via a single –CH2– spacer. An isotope effect probe is suggested to detect this mechanistic changeover.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 106064 |
| Deposited On: | 02 Aug 2017 06:40 |
| Last Modified: | 02 Aug 2017 06:40 |
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