Davis, Franklin A. ; Prasad, Kavirayani R. ; Nolt, M. Brad ; Wu, Yongzhong (2003) N-sulfinyl β-amino weinreb amides: synthesis of enantiopure β-amino carbonyl compounds. Asymmetric synthesis of (+)-sedridine and (-)-allosedridine Organic Letters, 5 (6). pp. 925-927. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol034119z
Related URL: http://dx.doi.org/10.1021/ol034119z
Abstract
N-Sulfinyl β-amino Weinreb amides are prepared by condensation of sulfinimines with the potassium enolate of N-methoxy-N-methylacetamide. These new chiral building blocks are useful for the asymmetric synthesis of β-amino carbonyl compounds, as illustrated here by the concise enantioselective syntheses of sedum alkaloids (+)-sedridine and (−)-allosedridine.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 106025 |
| Deposited On: | 21 Dec 2017 12:02 |
| Last Modified: | 21 Dec 2017 12:02 |
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