Kona, Chandrababu Naidu ; Ramana, Chepuri V. (2014) Gold(I)-catalysed [1,3] O→C rearrangement of allenyl ethers Chemical Communications, 50 (17). pp. 2152-2154. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...
Related URL: http://dx.doi.org/10.1039/C3CC49629E
Abstract
A simple and rapid access to the α-substituted acryl aldehydes has been provided by developing a gold-catalysed [1,3] rearrangement of the allenyl ethers importantly with a record turnover frequency of 4600 h−1 (at 0.05 mol% of the catalyst concentration) in homogeneous gold(I) catalysis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 105991 |
| Deposited On: | 01 Feb 2018 16:52 |
| Last Modified: | 01 Feb 2018 16:52 |
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