Vadhadiya, Paresh M. ; Ramana, C. V. (2014) Total synthesis of mangiferaelactone Tetrahedron Letters, 55 (45). pp. 6263-6265. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2014.09.084
Abstract
Herein we document the first total synthesis of mangiferaelactone and thus establish its absolute configuration. The central nonenolide ring was constructed using ring closing metathesis and Yamaguchi esterification. The key alcohol fragment was synthesized by the Bernet–Vasella fragmentation of C-ribofuranoside.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Total Synthesis; Nonenolide; Ring Closing Metathesis; Bernet–Vasella Fragmentation; Yamaguchi Protocol |
| ID Code: | 105928 |
| Deposited On: | 01 Feb 2018 16:50 |
| Last Modified: | 01 Feb 2018 16:50 |
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