Suneel Kumar, Chepuri V. ; Ramana, Chepuri V. (2015) Ru-catalyzed redox-neutral cleavage of the N–O bond in isoxazolidines: Isatogens to pseudoindoxyls via a one-pot [3 + 2]-cycloaddition/N–O cleavage Organic Letters, 17 (12). pp. 2870-2873. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b...
Related URL: http://dx.doi.org/10.1021/acs.orglett.5b00837
Abstract
A novel metal-catalyzed oxygen atom transfer reaction onto olefins is reported. By taking isatogens as substrates, a one-pot [3 + 2]-cycloaddition of nitrone with olefins followed by the Ru-catalyzed redox-neutral N–O bond cleavage of intermediate isoxazolidine has been executed as a simple method for the synthesis of 2,2-disubstituted pseudoindoxyls.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Americal Chemical Society. |
| ID Code: | 105918 |
| Deposited On: | 01 Feb 2018 16:50 |
| Last Modified: | 01 Feb 2018 16:50 |
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