Paymode, Dinesh J. ; Ramana, Chepuri V. (2015) Ruthenium(II)-catalyzed C3 arylation of 2-aroylbenzofurans with arylboronic acids/aryltrifluoroborates via carbonyl-directed C–H bond activation Journal of Organic Chemistry, 80 (22). pp. 11551-11558. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/acs.joc.5b0193...
Related URL: http://dx.doi.org/10.1021/acs.joc.5b01932
Abstract
The Ru(II)-catalyzed carbonyl-directed C–H activation with (hetero)arylboron reagents has been executed for the synthesis of 2-aroyl-3-(hetero)arylbenzofurans. A hypothesis founded upon the involvement of an active carbonatoruthenium(II) complex for a coordinative insertion and the aerobic oxidation of the in situ generated Ru(0) to Ru(II), to continue the catalytic cycle, has been extended.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 105912 |
| Deposited On: | 01 Feb 2018 16:49 |
| Last Modified: | 01 Feb 2018 16:49 |
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