Prasad, Kavirayani R. ; Anbarasan, Pazhamalai (2006) Stereoselective synthesis of (+)-boronolide and (−)-5-epi-boronolide Tetrahedron: Asymmetry, 17 (7). pp. 1146-1151. ISSN 0957-4166
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetasy.2006.03.028
Abstract
Stereoselective synthesis of boronolide and 5-epi-boronolide was achieved from D-(−)-tartaric acid. The key step involves the reduction of a keto Weinreb amide for the synthesis of boronolide, and a single pot construction of a diketone from the bis-Weinreb amide of tartaric acid and subsequent reduction with L-Selectride for 5-epi-boronolide.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 105853 |
Deposited On: | 21 Dec 2017 12:04 |
Last Modified: | 21 Dec 2017 12:04 |
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