Prasad, Kavirayani R. ; Chandrakumar, Appayee (2006) Nucleophilic addition reactions of 1,4-diketones derived from tartaric acid: synthesis of TADDOL analogues Synthesis, 2006 (13). pp. 2159-2166. ISSN 0039-7881
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Official URL: https://www.thieme-connect.de/DOI/DOI?10.1055/s-20...
Related URL: http://dx.doi.org/10.1055/s-2006-942422
Abstract
A systematic investigation of the reduction and Grignard reagents addition to 1,4-diketones derived from tartaric acid was carried out. It was found that the reduction proceeded with high selectivity using K-Selectride as the reducing agent; while Grignard reagent addition was highly dependent on structure of the dione as well as on the Grignard reagent. The resultant 1,4-diols represent a series of novel TADDOL analogues.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers Inc. |
| Keywords: | Asymmetric Synthesis; TADDOL; Stereoselective Addition |
| ID Code: | 105842 |
| Deposited On: | 21 Dec 2017 12:05 |
| Last Modified: | 21 Dec 2017 12:05 |
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