Pandey, D. S. ; Mishra, R. L. ; Mishra, A. ; Agarwala, U. C. (1990) Reactions of [Ruh(CO)Cl(EPh3)3] (E = P, As) and [Ru(η5-C5H5)ClL2] [L2 = (PPh3)2, (AsPh3)2, dppe, dppm] with 4-cyanopyridine, 1,4-dicyanobenzene and 1,4-dicyanobutene Polyhedron, 9 (17). pp. 2153-2162. ISSN 0277-5387
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)84047-4
Abstract
Reactions of [RuH(CO)Cl(EPh3)3] (E = P, As) with 4-cyanopyridine, 1,4-dicyanobenzene, 1,4-dicyanobutene and of [Ru(η5-C5H5)ClL2] [L2 = (PPh3)2, (AsPh3)2, dppe, dppm] with 1,4-dicyanobenzene in the presence of anions like BF4−, PF6−, BPh4−, ClO4−, have been carried out. Cyanopyridine containing hydridocarbonyl complexes showed a marked tendency to react with halogenated solvents yielding complexes containing no hydride ions. The cationic mononuclear, binuclear and neutral complexes have been characterized by elemental analyses and spectral (IR, UV—vis, 1H and 13C NMR) studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 105726 |
| Deposited On: | 20 Apr 2017 05:40 |
| Last Modified: | 20 Apr 2017 05:42 |
Repository Staff Only: item control page
