Reactions of [RuH(CO)C1(EPh3)3] (E = PPh3, AsPh3) with 1-piperidinecarbonitrile and 1,4-piperazinedicarbonitrile in the presence of an anion (BF4, PF6, BPh4 and CH3C6H4SO3)

Pandey, D. S. ; Mishra, A. ; Agarwala, U. C. (1990) Reactions of [RuH(CO)C1(EPh3)3] (E = PPh3, AsPh3) with 1-piperidinecarbonitrile and 1,4-piperazinedicarbonitrile in the presence of an anion (BF4, PF6, BPh4 and CH3C6H4SO3) Inorganica Chimica Acta, 172 (1). pp. 13-18. ISSN 0020-1693

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0020-1693(00)80443-0

Abstract

Reactions of 1-piperidinecarbonitrile and 1,4-piperazinecarbonitrile with [RuH(CO)Cl(EPh3)3] (E=P, As) have been carried out in the presence of suitable anions such as BF4, PF6, BPh4 and CH3C6H4SO3. The reaction products have been characterized using various physicochemical techniques: elemental analyses, magnetic measurements, melting points, conductivity measurements, IR, UV=Vis, 1H and 13C NMR spectroscopy.

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