Synthetic and spectroscopic aspects of some maleonitrile dithiolate complexes of ruthenium(II)

Gupta, D. K. ; Sisodia, O. S. ; Sahay, A. N. ; Pandey, D. S. (1998) Synthetic and spectroscopic aspects of some maleonitrile dithiolate complexes of ruthenium(II) Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 28 (3). pp. 355-365. ISSN 0094-5714

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0094571...

Related URL: http://dx.doi.org/10.1080/00945719809349360

Abstract

Reactions of [RuH(CO)Cl(PPh3)3] with Na2S2C2(CN), (referred hereafter as Na2mnt) lead to the formation of [RuH(CO)(PPh3),{S2C2(CN)2}] which, upon treatment with [RuCp(EPh3)2Cl], yields neutral complexes with the general formulation [RuH(CO)(EPh3)2{S2C2(CN)2)RuCp(EPh3)] (E = P, As, Sb). These complexes have been characterized by various physico-chemical techniques (elemental analyses, IR, 1H, 13C and 31P NMR and electronic spectra).

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