Prasad, Kavirayani R. ; Gutala, Phaneendra (2011) Enantioselective total synthesis of macrosphelides A and E Tetrahedron, 67 (25). pp. 4514-4520. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tet.2011.04.099
Abstract
Enantioselective synthesis of 16-membered trilactone macrolides, macrosphelide A and E from (S)-lactic acid is described. Key features of the synthesis include the utility of a hitherto unexplored β-ketophosphonate derived from lactic acid and Yamaguchi lactonization leading to the title compounds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Total Synthesis; Macrolactone; Lactic Acid; Macrosphelides |
| ID Code: | 105701 |
| Deposited On: | 21 Dec 2017 12:04 |
| Last Modified: | 21 Dec 2017 12:04 |
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