Prasad, Kavirayani R. ; Penchalaiah, Kamala (2011) Enantiodivergent total synthesis of microcarpalide from L-tartaric acid Tetrahedron, 67 (23). pp. 4268-4276. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tet.2011.03.102
Abstract
Stereoselective approach for the synthesis of both enantiomers of bio-active decanolactone microcarpalide is described from L-tartaric acid. The synthesis of the key intermediates en route to the natural product is achieved from L-tartaric acid involving the elaboration of γ-hydroxy amide derived from tartaric acid and ring opening of an epoxide derived from tartaric acid.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Decanolide; Microcarpalide; Tartaric Acid; Total Synthesis |
ID Code: | 105699 |
Deposited On: | 21 Dec 2017 12:03 |
Last Modified: | 21 Dec 2017 12:03 |
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