Total synthesis of panaxytriol and panaxydiol

Prasad, Kavirayani R. ; Swain, Bandita (2011) Total synthesis of panaxytriol and panaxydiol Tetrahedron: Asymmetry, 22 (12). pp. 1261-1265. ISSN 0957-4166

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetasy.2011.07.007

Abstract

The enantioselective total synthesis of the diyne containing natural products panaxytriol and (3S,10R)-panaxydiol from l-tartaric acid is reported. Key steps in the synthesis include the elaboration of a γ-hydroxy amide derived from tartaric acid to the required alkyne and the formation of the desired diyne unit by a Cadiot–Chodkiewicz coupling.

Item Type:Article
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ID Code:105698
Deposited On:21 Dec 2017 12:05
Last Modified:21 Dec 2017 12:05

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