Prasad, Kavirayani R. ; Gutala, Phaneendra (2012) Total synthesis of (+)-phomopsolide B Tetrahedron, 68 (36). pp. 7489-7493. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tet.2012.06.002
Abstract
An enantiospecific total synthesis of polyhydroxy δ-pyrone natural product phomopsolide B is accomplished. The main feature of the synthesis is the installation of the required E-olefin by Horner–Emmons–Wordsworth reaction and the formation of the lactone involving Still–Gennari olefination followed by lactonization.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Phomopsolide B; Polyhydroxy Lactone; δ-Pyrone |
ID Code: | 105692 |
Deposited On: | 21 Dec 2017 12:04 |
Last Modified: | 21 Dec 2017 12:04 |
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