Punniyamurthy, T. ; Irie, Ryo ; Katsuki, Tsutomu ; Akita, Munetaka ; Moro-oka, Yoshihiko (1999) Why do (R,R)- and (R,S)-(salen)manganese(III) complexes show different substrate-specificity? the role of an apical aqua ligand Synlett, 1999 (7). pp. 1049-1052. ISSN 0936-5214
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Official URL: https://www.thieme-connect.com/products/ejournals/...
Related URL: http://dx.doi.org/10.1055/s-1999-2785
Abstract
The structure of (R,R)-(salen)manganese(III) complex (2) possessing axial chirality as a chiral element was determined unambiguously by X-ray analysis. The central manganese ion of 2 is coordinated by two aqua ligands at the apical sites. The attractive interaction between the aqua ligand and the 2'-phenyl group in the C3-naphthyl substituent affects the ligand conformation and, in turn, influences the asymmetric induction by 2.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers Inc. |
| Keywords: | (Salen)manganese(III) Complex; Asymmetric Oxidation; Apical Aqua Ligand; Ligand Conformation |
| ID Code: | 105671 |
| Deposited On: | 22 Jun 2017 10:47 |
| Last Modified: | 22 Jun 2017 10:48 |
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