Metri, Prashant K. ; Schiess, Raphael ; Prasad, Kavirayani R. (2012) Enantiospecific total synthesis of (-)-bengamide E Chemistry - An Asian Journal, 8 (2). pp. 488-493. ISSN 1861-4728
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/asia.20...
Related URL: http://dx.doi.org/10.1002/asia.201200999
Abstract
Total synthesis of the polyhydroxy caprolactam amide natural product, bengamide E, is accomplished starting from tartaric acid. Key reactions in the synthesis include desymmetrization of the bis(dimethylamide) unit of tartaric acid, Zn(BH4)2-mediated anti-selective reduction, and a Horner–Wadsworth–Emmons olefination.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 105652 |
| Deposited On: | 21 Dec 2017 12:01 |
| Last Modified: | 21 Dec 2017 12:01 |
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