Punniyamurthy, T. ; Reddy, M. Madhava ; Kalra, S. J. S. ; Iqbal, J. (1996) Cobalt(II) Schiff base catalyzed biomimetic oxidation of organic substrates with dioxygen Pure and Applied Chemistry, 68 (3). pp. 619-622. ISSN 0033-4545
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Official URL: https://www.iupac.org/publications/pac/68/3/0619/i...
Related URL: http://dx.doi.org/10.1351/pac199668030619
Abstract
Cobalt(II) Schzrbase complexes 1, 2 and 3 catalyze the oxidation of a wide range of organic substrates in the presence of carbonyl compounds and dioxygen. EPR studies on 1 indicate that these reactions are proceeding via a cobalt(1II)-superoxo complex formed under the aegis of carbonyl compounds and dioxygen. Catalysts 1-3 exhibit diverse reactivity profile and this has been attributed to the nature of ligand around cobalt which causes the formation of direrent active species from dioxygen.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to International Union of Pure and Applied Chemistry. |
| ID Code: | 105637 |
| Deposited On: | 22 Jun 2017 10:34 |
| Last Modified: | 22 Jun 2017 10:35 |
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