Bali, Amit K. ; Sunnam, Sunil K. ; Prasad, Kavirayani R. (2014) Enantiospecific total synthesis of macrolactone Sch 725674 Organic Letters, 16 (15). pp. 4001-4003. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol5018678
Related URL: http://dx.doi.org/10.1021/ol5018678
Abstract
The enantiospecific total synthesis of 14-membered macrolactone Sch 725674 was accomplished from tartaric acid. Key reactions in the synthesis include the Ley’s dithiaketalization of an alkynone derived from the bis-Weinreb amide of tartaric acid, Boord olefination, and ring-closing metathesis of an acrylate ester.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 105629 |
| Deposited On: | 21 Dec 2017 12:02 |
| Last Modified: | 21 Dec 2017 12:02 |
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