Kumar, S. Mothish ; Prasad, Kavirayani R. (2014) Enantiospecific formal total synthesis of iriomoteolide 3a Chemistry - An Asian Journal, 9 (12). pp. 3431-3439. ISSN 1861-4728
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/asia.20...
Related URL: http://dx.doi.org/10.1002/asia.201402593
Abstract
A formal total synthesis of the marine macrolide iriomoteolide 3a is described. Salient features of the synthesis include the elaboration of a β-keto phosphonate derived from D-(−)-tartaric acid and the extension of a chiral butyrolactone derived from L-glutamic acid. Ring-closing metathesis is employed to construct the macrolactone core of the natural product.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Iriomoteolide 3a; Lactones; Macrocycles; Natural Products; Total Synthesis |
| ID Code: | 105620 |
| Deposited On: | 21 Dec 2017 12:01 |
| Last Modified: | 21 Dec 2017 12:01 |
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