Revu, Omkar ; Prasad, Kavirayani R. (2017) Total Synthesis of the Bis-silyl Ether of (+)-15-epi-Aetheramide A The Journal of Organic Chemistry, 82 (1). pp. 438-460. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b0253...
Related URL: http://dx.doi.org/10.1021/acs.joc.6b02535
Abstract
Synthesis of the macrolactone depsipeptide aetheramide A was attempted by three different approaches. The first approach to form the macrolactone involving macrolactonization to form the C1–C21 bond and the second approach using a ring-closing metathesis (RCM) strategy to form the C10–C11 olefinic bond failed. The third approach starting from R-mandelic acid, involving the RCM reaction to install the C18–C19 ring junction, was successful in assembling the macrolactone.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 105612 |
| Deposited On: | 21 Dec 2017 12:02 |
| Last Modified: | 21 Dec 2017 12:02 |
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