Yadav, Mahendra ; Kumar, Prashant ; Singh, Ashish Kumar ; Ribas, Joan ; Pandey, Daya Shankar (2009) First examples of homo-/heteroleptic bi-/tri-nuclear complexes containing 5-ferrocenyldipyrromethene Dalton Transactions (44). pp. 9929-9934. ISSN 0300-9246
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2009...
Related URL: http://dx.doi.org/10.1039/B914215K
Abstract
The first examples of homo- and heteroleptic complexes containing 5-ferrocenyldipyrromethene (fcdpm) [Cu(fcdpm)2] (1) [Cu(fcdpm)(acac)] (2), [Ni(fcdpm)(acac)] (3) and [Zn(fcdpm)2] (4) (acac = acetylacetonato) are described. Formation of the asymmetric metal complexes has been followed by electronic absorption and infrared spectroscopy. The complexes have been characterised by elemental analyses and spectral studies. Structures of [Cu(fcdpm)2] (1), [Cu(fcdpm)(acac)] (2) and [Ni(fcdpm)(acac)] (3) have been determined crystallographically. Structural data revealed that the metal centre in the copper complexes [Cu(fcdpm)2] (1), [Cu(fcdpm)(acac)] (2) and the nickel complex [Ni(fcdpm)(acac)] (3) adopts a distorted square planar geometry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 105459 |
| Deposited On: | 20 Apr 2017 11:02 |
| Last Modified: | 20 Apr 2017 11:02 |
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