Yadav, Mahendra ; Kumar, Prashant ; Pandey, Daya Shankar (2010) Heteroleptic rhodium complexes containing both the dipyrrin/cyclooctadiene ligands and application of [(η4-C8H12)Rh(4-pyrdpm)] in the construction of homo-/hetero-bimetallic complexes Polyhedron, 29 (2). pp. 791-800. ISSN 0277-5387
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.poly.2009.10.028
Abstract
Heteroleptic rhodium(I) complexes with the general formulations [(η4-C8H12)Rh(L)] [η4-C8H12=1,5-cyclooctadiene; L=5-(4-cyanophenyl)dipyrromethene, cydpm; 5-(4-nitrophenyl)dipyrromethene, ndpm; and 5-(4-benzyloxyphenyl)dipyrromethene, bdpm; 5-(4-pyridyl)dipyrromethene, 4-pyrdpm; 5-(3-pyridyl)dipyrromethene, 3-pyrdpm] have been synthesized. The complex [(η4-C8H12)Rh(4-pyrdpm)] have been used as a synthon in the construction of homo-bimetallic complex [(η4-C8H12)Rh(μ-4-pyrdpm)Rh(η5-C5Me5)Cl2] and hetero-bimetallic complexes [(η4-C8H12)Rh(μ-4-pyrdpm)Ir(η5-C5Me5)Cl2], [(η4-C8H12)Rh(μ-4-pyrdpm)Ru(η6-C10H14)Cl2] and [(η4-C8H12)Rh(μ-4-pyrdpm)Ru(η6-C6H6)Cl2]. Resulting complexes have been characterized by elemental analyses and spectral studies. Molecular structures of the representative mononuclear complexes [(η4-C8H12)Rh(ndpm)] and [(η4-C8H12)Rh(4-pyrdpm)] have been authenticated crystallographically.
Item Type: | Article |
---|---|
Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Rhodium; Heteroleptic; Dipyrrins; Homo-/Hetero-Bimetallic Complexes |
ID Code: | 105373 |
Deposited On: | 20 Apr 2017 11:05 |
Last Modified: | 20 Apr 2017 11:05 |
Repository Staff Only: item control page