Yadav, Mahendra ; Singh, Ashish Kumar ; Pandey, Daya Shankar (2011) Heteroleptic half-sandwich Ru(II), Rh(III) and Ir(III) complexes based on 5-ferrocenyldipyrromethene Journal of Organometallic Chemistry, 696 (3). pp. 758-763. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2010.09.070
Abstract
The synthesis and characterization of heteroleptic complexes with the formulations [(η6-arene)RuCl(fcdpm)] (η6-arene = C6H6, C10H14) and [(η5-C5Me5)MCl(fcdpm)] (M = Rh, Ir; fcdpm = 5-ferrocenyldipyrromethene) have been reported. All the complexes have been characterized by elemental analyses, IR, 1H NMR and electronic spectral studies. Structures of [(η6-C6H6)RuCl(fcdpm)] and [(η6-C10H14)RuCl(fcdpm)] have been determined crystallographically. Chelating monoanionic linkage of fcdpm to the respective metal centres has been supported by spectral and structural studies. Further, reactivity of the representative complex [(η6-C10H14)RuCl(fcdpm)] with ammonium thiocyanate (NH4SCN) and triphenylphosphine (PPh3) have been examined.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Ruthenium(II); Rhodium(III); Iridium(III); Piano-Stool Complexes; 5-Ferrocenyl-Dipyrromethene |
| ID Code: | 105333 |
| Deposited On: | 20 Apr 2017 11:16 |
| Last Modified: | 20 Apr 2017 11:16 |
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