Heteroleptic half-sandwich Ru(II), Rh(III) and Ir(III) complexes based on 5-ferrocenyldipyrromethene

Yadav, Mahendra ; Singh, Ashish Kumar ; Pandey, Daya Shankar (2011) Heteroleptic half-sandwich Ru(II), Rh(III) and Ir(III) complexes based on 5-ferrocenyldipyrromethene Journal of Organometallic Chemistry, 696 (3). pp. 758-763. ISSN 0022-328X

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.jorganchem.2010.09.070

Abstract

The synthesis and characterization of heteroleptic complexes with the formulations [(η6-arene)RuCl(fcdpm)] (η6-arene = C6H6, C10H14) and [(η5-C5Me5)MCl(fcdpm)] (M = Rh, Ir; fcdpm = 5-ferrocenyldipyrromethene) have been reported. All the complexes have been characterized by elemental analyses, IR, 1H NMR and electronic spectral studies. Structures of [(η6-C6H6)RuCl(fcdpm)] and [(η6-C10H14)RuCl(fcdpm)] have been determined crystallographically. Chelating monoanionic linkage of fcdpm to the respective metal centres has been supported by spectral and structural studies. Further, reactivity of the representative complex [(η6-C10H14)RuCl(fcdpm)] with ammonium thiocyanate (NH4SCN) and triphenylphosphine (PPh3) have been examined.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Ruthenium(II); Rhodium(III); Iridium(III); Piano-Stool Complexes; 5-Ferrocenyl-Dipyrromethene
ID Code:105333
Deposited On:20 Apr 2017 11:16
Last Modified:20 Apr 2017 11:16

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