Vanga, Devendar G. ; Kaliappan, Krishna P. (2014) Total syntheses of rubiginone A2, C2, and fujianmycin A RSC Advances, 4 (25). pp. 12716-12722. ISSN 2046-2069
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2014...
Related URL: http://dx.doi.org/10.1039/C3RA47775D
Abstract
The total syntheses of rubiginone A2, C2 and fujianmycin A are described. The synthesis involves Diels–Alder/aromatization and photo chemical reactions as key steps to construct the tetracyclic frame of benz[a]anthraquinone skeleton. Sharpless epoxidation, a copper-catalyzed regioselective epoxide opening, and enyne metathesis reactions are utilized as the key steps for the synthesis of chiral vinylcyclohexene.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 105022 |
| Deposited On: | 19 May 2017 09:00 |
| Last Modified: | 19 May 2017 09:00 |
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