Palanichamy, Kalanidhi ; Subrahmanyam, Ayyagari V. ; Kaliappan, Krishna P. (2011) A radical cyclization approach to the formal total syntheses of platencin Organic & Biomolecular Chemistry, 9 (22). pp. 7877-7886. ISSN 1477-0520
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2011...
Related URL: http://dx.doi.org/10.1039/C1OB06155K
Abstract
Two different strategies leading to formal total syntheses of platencin are described. The first strategy involving Claisen rearrangement and radical cyclization provides a rapid access to the core structure of platencin, and also use minimum protective-group operations. The second strategy, a protecting group-free route, utilizes a 6-exo-trig radical cyclization and aldol condensation as key steps leading to the formal synthesis of platencin.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 104994 |
| Deposited On: | 19 May 2017 09:34 |
| Last Modified: | 19 May 2017 09:34 |
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