Meso-pyrrole-substituted 22-oxacorroles: building blocks for the synthesis of bodipy-bridged 22-oxacorrole dyads

Kalita, Hemanta ; Ravikanth, Mangalampalli (2015) Meso-pyrrole-substituted 22-oxacorroles: building blocks for the synthesis of bodipy-bridged 22-oxacorrole dyads Chemistry - A European Journal, 21 (20). pp. 7399-7402. ISSN 0947-6539

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...

Related URL: http://dx.doi.org/10.1002/chem.201500702

Abstract

Novel boron-dipyrromethene (BODIPY)-bridged 22-oxacorrole dyads, using meso-pyrrolyl 22-oxacorrole as a key synthon, have been synthesized. The reactivity of the meso-pyrrolyl group of 22-oxacorrole was exploited to synthesize the first examples of BODIPY-bridged 22-oxacorrole dyads in ≈40% yield. The dyads are stable and exhibited interesting spectral and electrochemical properties.

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Deposited On:30 Nov 2017 12:18
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