Sharma, Ritambhara ; Ghosh, Avijit ; Wolfram, Benedikt ; Broring, Martin ; Ravikanth, Mangalampalli (2013) Synthesis and characterization of hexa-coordinated Sn(iv) complexes of meso-aryl dipyrrins Dalton Transactions, 42 (16). pp. 5627-5630. ISSN 1477-9226
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2013...
Related URL: http://dx.doi.org/10.1039/C3DT00031A
Abstract
Our successful synthesis of the first examples of Sn(IV) complexes of meso-aryl dipyrrins is reported. Sn(IV) dipyrrins are synthesized by treating meso-aryl dipyrrins with readily available SnCl2•2H2O in pyridine at reflux temperature and isolated as pure complexes by recrystallization. The X-ray structure revealed that the complex is hexa-coordinated and the Sn(IV) ion is coordinated to two dipyrrin units and two chlorides with overall appearance of a butterfly like structure. The complexes are stable in solution and characterized by spectral and electrochemical techniques.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 104789 |
| Deposited On: | 30 Nov 2017 12:35 |
| Last Modified: | 30 Nov 2017 12:35 |
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