Lakshmi, Vellanki ; Ravikanth, Mangalampalli (2011) Synthesis of sterically crowded polyarylated boron-dipyrromethenes The Journal of Organic Chemistry, 76 (20). pp. 8466-8471. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo2010022
Related URL: http://dx.doi.org/10.1021/jo2010022
Abstract
A rapid synthetic route for polyarylated boron-dipyrromethenes using hexabromo boron-dipyrromethene as the key synthon is described. The X-ray structure revealed that the polyarylated BODIPY adopts a propeller-like conformation. These compounds exhibit red-shifted absorption and fluorescence bands with decent quantum yields and reversible oxidation and reduction waves when compared to unsubstituted boron-dipyrromethenes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 104618 |
| Deposited On: | 30 Nov 2017 12:32 |
| Last Modified: | 30 Nov 2017 12:32 |
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