Rajeswara Rao, Malakalapalli ; Ravikanth, Mangalampalli (2011) Boron complexes of oxasmaragdyrin, a core-modified expanded porphyrin The Journal of Organic Chemistry, 76 (9). pp. 3582-3587. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo200295b
Related URL: http://dx.doi.org/10.1021/jo200295b
Abstract
We report the synthesis of first examples of BF2 and B(OR) 2 complexes of oxasmaragdyrin, the expanded core-modified porphyrin, in decent yields under very simple reaction conditions at room temperature. The boron complexation of oxasmaragdyrin alters the electronic properties of the macrocycle significantly as evident by various spectroscopic techniques. Our preliminary studies indicated that the B(OH) 2−smaragdyrin complex can act as a selective neutral fluoride ion sensor.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 104611 |
| Deposited On: | 30 Nov 2017 12:32 |
| Last Modified: | 30 Nov 2017 12:32 |
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