Agarwal, Neeraj ; Hung, C. H. ; Ravikanth, Mangalampalli (2004) Synthesis and crystal structures of 2,3,12,13-tetraalkoxy-21,23-dithiaporphyrins and 2,3-dialkoxy-21-monothiaporphyrins Tetrahedron, 60 (47). pp. 10671-10680. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tet.2004.09.008
Abstract
The tetraalkoxy and dialkoxy substituted 21,23-dithiaporphyrins and 21-monothiaporphyrins, respectively, having methoxy, butoxy, octyloxy and dodecyloxy substituents at β-thiophene carbons were synthesized and characterized. The X-ray structure was solved for tetrabutoxy substituted 21,23-dithiaporphyrin and it exhibited a more planar structure compared with unsubstituted S2TPP, whereas the dimethoxy substituted 21-monothiaporphyrin showed a saddle shaped structure similar to unsubstituted STPPH.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Monothiaporphyrin; Dithiaporphyrin; STPPH |
| ID Code: | 104540 |
| Deposited On: | 01 Dec 2017 10:51 |
| Last Modified: | 01 Dec 2017 10:51 |
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