Synthesis of mono meso-pyridyl 21,23-dithiaporphyrins and unsymmetrical non-covalent dimers

Punidha, Sokkalingam ; Ravikanth, Mangalampalli (2004) Synthesis of mono meso-pyridyl 21,23-dithiaporphyrins and unsymmetrical non-covalent dimers Tetrahedron, 60 (38). pp. 8437-8444. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2004.07.011

Abstract

A new method has been developed to synthesize 21,23-dithiaporphyrins having one pyridyl group at the meso position. The method required easily available unknown precursors and the condensation resulted in mono meso-pyridyl 21,23-dithiaporphyrins as single products in 8–11 % yield. Two of the three mono meso-pyridyl N2S2 porphyrins were used to synthesize non-covalent unsymmetrical porphyrin dimers containing one N2S2 and one N4 porphyrin cores.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Meso-pyridyl Porphyrins; Core-modified Porphyrins; Non-covalent; Unsymmetrical Array
ID Code:104533
Deposited On:01 Dec 2017 10:50
Last Modified:01 Dec 2017 10:50

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