Gupta, Iti ; Ravikanth, Mangalampalli (2003) Synthesis of meso-furyl porphyrins with N4, N3S, N2S2 and N3O porphyrin cores Tetrahedron, 59 (32). pp. 6131-6139. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(03)00950-5
Abstract
A series of meso-furyl porphyrins with four different porphyrin cores (N4, N3S, N2S2 and N3O) were synthesized and characterized. The comparison of NMR, optical and fluorescence properties of meso-furyl porphyrins with porphyrins with six-membered aryl groups indicates that electronic properties of porphyrins were changed drastically on the introduction of furyl groups at meso positions. The maximum shifts in spectral bands were observed for meso-furyl porphyrins with N2S2 core. On protonation, the absorption bands of meso-furyl porphyrins were further red shifted. All these changes were ascribed to the possibility of more planarity of the meso-furyl porphyrins due to the small size of the furyl groups which results in extending the π-delocalisation of the porphyrin ring in to the furyl groups.due to the small size of the furyl groups which results in extending the π-delocalisation of the porphyrin ring in to the furyl groups.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Meso-furyl Porphyrins; Core-modified Porphyrins; Bathochromic Shifts; Porphyrin Planarity |
ID Code: | 104524 |
Deposited On: | 01 Dec 2017 10:50 |
Last Modified: | 01 Dec 2017 10:50 |
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