Ramakrishna, Kota ; Kaliappan, Krishna P. (2015) An enantioselective total synthesis of Sch-725674 Organic and Biomolecular Chemistry, 13 (1). pp. 234-240. ISSN 1477-0520
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2015...
Related URL: http://dx.doi.org/10.1039/C4OB02136C
Abstract
An enantioselective total synthesis of Sch-725674, a unique 14-membered macrolactone, has been accomplished in 13 steps. The step-wise dithiane alkylation served as a strategic step to assemble the upper and lower fragments of the molecule, whereas cross metathesis reaction, Yamaguchi macrolactonization and a substrate controlled stereoselective reduction are used as key steps to complete the total synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
| ID Code: | 103950 |
| Deposited On: | 12 Jun 2017 09:48 |
| Last Modified: | 12 Jun 2017 09:54 |
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