Dey, Santu ; Datta, Dhrubajyoti ; Chakraborty, Kaustav ; Nandi, Surajit ; Anoop, Anakuthil ; Pathak, Tanmaya (2013) A coordination-assisted general approach to nickel-based nano metallogels RSC Advances, 3 . pp. 9163-9166. ISSN 2046-2069
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2013...
Related URL: http://dx.doi.org/10.1039/C3RA41178H
Abstract
NiCl2·6H2O, in the presence of a wide range of amines, forms a green gel in protic solvents. UV-Vis studies indicate the initial formation of a square planar species which is transformed into tetrahedral or octahedral components. Theoretical studies indicate the presence of cis-Ni(OMe)2(MeOH)4 as one of the major components of the gel. This study reveals that metallogel formation does not necessarily require synthetically designed ligands with pre-defined coordination sites.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 103919 |
| Deposited On: | 17 Mar 2017 12:04 |
| Last Modified: | 17 Mar 2017 12:04 |
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