Homochiral coordination polymeric gel: Zn2+-induced conformational changes leading to J-aggregated helical fibres formation

Dubey, Mrigendra ; Kumar, Ashish ; Pandey, Daya Shankar (2014) Homochiral coordination polymeric gel: Zn2+-induced conformational changes leading to J-aggregated helical fibres formation Chemical Communications, 50 (14). pp. 1675-1677. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2014...

Related URL: http://dx.doi.org/10.1039/C3CC47359G

Abstract

A novel chiral coordination polymeric gel based on an amino acid derived symmetrical ligand, specific base, and Zn2+ has been described. Zn2+ induced conformational reorganization in the ligand leads to gelation via J-aggregated helical fibres. The vital role played by π–π stacking in gelation has been monitored by fluorescence and NMR spectroscopy.

Item Type:Article
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ID Code:103888
Deposited On:21 Apr 2017 06:32
Last Modified:21 Apr 2017 06:32

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