Li+-induced selective gelation of discrete homochiral structural isomers derived from L-tartaric acid

Dubey, Mrigendra ; Kumar, Ashish ; Gupta, Rakesh Kumar ; Pandey, Daya Shankar (2014) Li+-induced selective gelation of discrete homochiral structural isomers derived from L-tartaric acid Chemical Communications, 50 (60). pp. 8144-8147. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...

Related URL: http://dx.doi.org/10.1039/C4CC02591A

Abstract

Two chiral structural isomers have been synthesized by molecular engineering of L-tartaric acid. In the presence of LiOH isomer 1 forms a thermally stable, fluorescent gel which exhibits interesting nano-cluster morphology, anomalous optical and rheological properties whilst 2 forms a non-fluorescent solution under similar conditions. The current–voltage (I–V) curve followed a non-linear trend, rationally in close proximity to the diode characteristic curve.

Item Type:Article
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